Overview: two grades, one family, one decisive difference
X20CrMoWV12-1 (EN 1.4935) and X22CrMoV12-1 (EN 1.4923) are 12% chromium martensitic heat-resistant steels governed by EN 10302:2008, both supplied in the quenched-and-tempered condition. The sole but critical alloying difference is tungsten (W): 1.4935 contains 0.40–0.60 wt% W; 1.4923 contains none.
At service temperatures below 530 °C, the practical performance difference between these two grades is small enough that cost and availability typically decide the choice. Above 530 °C, however, the tungsten in 1.4935 delivers measurably superior creep rupture strength — up to 40% higher at 600 °C — and substantially better long-term microstructural stability. Getting this selection wrong costs real engineering value: using 1.4923 above its thermal limit accelerates creep damage and shortens component life; using 1.4935 where 1.4923 suffices adds material cost with no performance return. For full chemical composition, mechanical data, and ordering details, see the X20CrMoWV12-1 (1.4935) forging specifications.
This guide draws on 25+ years of manufacturing both grades for power generation OEMs across Europe, North America, Asia, and the Middle East. Every data point and recommendation reflects direct production and field experience, not published abstracts alone.
Chemical composition: side-by-side per EN 10302:2008
The chemical composition of X20CrMoWV12-1 (1.4935) differs from X22CrMoV12-1 (1.4923) in one element only: tungsten (W) at 0.40–0.60 wt%, present in 1.4935 and absent in 1.4923.
All other primary alloying additions — chromium (10.5–12.5%), molybdenum (0.80–1.20%), vanadium (0.25–0.35%), and carbon (0.17–0.24%) — fall within overlapping ranges. This compositional similarity is why the grades are so frequently confused in procurement documents; the difference only manifests under the microscope and in long-term creep test data.
| Element | 1.4935 · X20CrMoWV12-1 | 1.4923 · X22CrMoV12-1 |
|---|---|---|
| C — Carbon | 0.17 – 0.24% | 0.18 – 0.24% |
| Cr — Chromium | 10.5 – 12.5% | 11.0 – 12.5% |
| Mo — Molybdenum | 0.80 – 1.20% | 0.80 – 1.20% |
| W — Tungsten | 0.40 – 0.60% KEY DIFFERENCE | Not specified — absent |
| V — Vanadium | 0.25 – 0.35% | 0.25 – 0.35% |
| Si — Silicon | ≤ 0.50% | ≤ 0.50% |
| Mn — Manganese | 0.50 – 1.00% | 0.50 – 1.00% |
| Ni — Nickel | ≤ 0.50% | ≤ 0.70% |
| S — Sulfur | ≤ 0.015% | ≤ 0.015% |
| P — Phosphorus | ≤ 0.025% | ≤ 0.025% |
Why tungsten (W) changes everything above 550 °C
Tungsten in X20CrMoWV12-1 (1.4935) raises high-temperature creep performance through two simultaneous mechanisms: solid-solution strengthening and carbide phase stabilization.
Mechanism 1 — Solid-solution strengthening
Tungsten atoms are significantly larger than iron atoms. When tungsten substitutes into the body-centred cubic (BCC) iron lattice — partially displacing molybdenum — the resulting lattice distortion creates stress fields that impede dislocation movement. The critical advantage over molybdenum alone is diffusion rate: at 550–600 °C, tungsten diffuses approximately 4–6× more slowly through the iron matrix than molybdenum. This means the solid-solution strengthening contribution remains thermally stable for far longer service durations — decisive for components designed for 100,000-hour service lives in gas and steam turbines.
Mechanism 2 — Carbide phase stability
At elevated service temperature, carbon migrates and forms carbide precipitates at grain boundaries and within the martensitic matrix. In 1.4923 (no tungsten), the dominant phases are M₂₃C₆ and M₇C₃, which Ostwald ripen relatively rapidly above 530 °C. Coarsened carbides lose their effectiveness as dislocation barriers — the primary microstructural cause of creep acceleration in long-term aged 1.4923 samples.
In 1.4935, the 0.50% W addition forms stable W-rich carbides (including MC-type) alongside the chromium-molybdenum carbides. These W-rich phases have substantially higher melting points and far lower coarsening kinetics. The fine carbide dispersion in 1.4935 therefore persists significantly longer above 550 °C — exactly where 1.4923 begins losing microstructural integrity.
The tungsten addition to 1.4935 is not a minor alloying refinement — it is an architectural decision that extends the thermally stable service range of a 12% Cr steel by 20–40 °C over multi-thousand-hour component lives.
Jiangsu Liangyi Co., Limited — Technical Engineering Team, Jiangyin, ChinaRoom-temperature mechanical properties: near identical
At room temperature and in the quenched-and-tempered (+QT) condition, X20CrMoWV12-1 (1.4935) and X22CrMoV12-1 (1.4923) are virtually identical in tensile strength, hardness, elongation, and impact toughness.
This near-identical room-temperature performance window is the primary reason these grades are confused in procurement: the tensile test results look the same. The divergence is exclusively a high-temperature, time-dependent (creep) phenomenon — which is why tensile testing alone cannot distinguish a correctly specified 1.4935 forging from an incorrectly supplied 1.4923 forging. Chemical analysis and elevated-temperature creep testing are the only reliable verification methods.
| Property (room temp., +QT condition) | 1.4935 · X20CrMoWV12-1 | 1.4923 · X22CrMoV12-1 |
|---|---|---|
| 0.2% Proof strength Rp0.2 (min.) | 590 MPa | 590 MPa |
| Tensile strength Rm | 780 – 980 MPa | 780 – 980 MPa |
| Elongation at fracture A (min.) | 15% | 15% |
| Reduction of area Z (min.) | 50% | 50% |
| Charpy-V longitudinal (min.) | 27 J | 27 J |
| Charpy-V transverse (min.) | 20 J | 20 J |
| Hardness (typical +QT range) | 248 – 302 HBW | 248 – 302 HBW |
Creep & elevated-temperature strength: where the grades diverge
Creep rupture strength — the maximum stress a material can sustain for a defined time at a defined temperature without fracturing — is the governing property for turbine blade and rotor specification. X20CrMoWV12-1 (1.4935) achieves 15–45% higher 100,000-hour creep rupture strength than X22CrMoV12-1 (1.4923) across the 550–600 °C range.
The following data is representative of EN 10302:2008 Annex A tabulated creep rupture values and published literature for both grades in the quenched-and-tempered condition. Values represent average material; minimum guaranteed values are typically 10–15% lower and should be used in component stress calculations.
| Temperature | 1.4935 — 100,000 h rupture strength | 1.4923 — 100,000 h rupture strength |
|---|---|---|
| 450 °C | 280 – 310 MPa | 265 – 300 MPa |
| 500 °C | 230 – 260 MPa | 215 – 245 MPa |
| 530 °C | 190 – 215 MPa | 175 – 200 MPa |
| 550 °C | 160 – 185 MPa +15–20% | 135 – 155 MPa |
| 575 °C | 115 – 140 MPa +25–30% | 85 – 110 MPa |
| 600 °C | 70 – 95 MPa +35–45% | 48 – 68 MPa |
The tungsten advantage compounds with temperature. At 550 °C, the 15–20% creep strength advantage of 1.4935 is meaningful but manageable in conservative designs. At 575 °C and above, the 25–45% gap fundamentally changes component wall thickness requirements, design life calculations, and planned inspection intervals for turbine operators. Jiangsu Liangyi supplies certified 1.4935 forgings with EN 10204 3.1 creep data for design verification.
Heat treatment: overlapping process, different tempering window
Both X20CrMoWV12-1 (1.4935) and X22CrMoV12-1 (1.4923) are heat-treated by austenitising, quenching in oil or forced air, and tempering. The key difference is the tempering temperature ceiling: 1.4935 allows up to 750 °C vs 720 °C for 1.4923, enabled by the thermal stability of W-rich carbides.
| Parameter | 1.4935 · X20CrMoWV12-1 | 1.4923 · X22CrMoV12-1 |
|---|---|---|
| Austenitising temperature | 1,050 – 1,100 °C | 1,000 – 1,080 °C |
| Austenitising hold time | 1 h per 25 mm section (min. 1 h) | 1 h per 25 mm section (min. 1 h) |
| Quench medium | Oil or forced air | Oil or forced air |
| Tempering temperature | 680 – 750 °C | 670 – 720 °C |
| Tempering hold time | 2 h per 25 mm (min. 2 h) | 2 h per 25 mm (min. 2 h) |
| Cooling from temper | Air or slow cool | Air or slow cool |
| Typical hardness result | 248 – 302 HBW | 248 – 302 HBW |
Weldability: conditionally weldable — strict procedures mandatory
Both X20CrMoWV12-1 (1.4935) and X22CrMoV12-1 (1.4923) are classified as conditionally weldable steels. High carbon equivalent values and strong hardenability make hydrogen-induced cold cracking (HICC) in the heat-affected zone (HAZ) the primary risk without adequate preheat, interpass temperature control, and post-weld heat treatment (PWHT).
| Parameter | 1.4935 · X20CrMoWV12-1 | 1.4923 · X22CrMoV12-1 |
|---|---|---|
| Weldability class | Conditionally weldable | Conditionally weldable |
| Preheat temperature | 200 – 300 °C | 200 – 300 °C |
| Interpass temperature (max.) | 350 °C | 350 °C |
| Post-weld heat treatment (PWHT) | 680 – 730 °C | 670 – 720 °C |
| Filler material | Matching 12% Cr filler with W (preferred) or ER410NiMo | Matching 12% Cr filler, e.g. ER410NiMo |
| Hydrogen control | Low-H electrode mandatory; diffusible H < 5 ml/100g weld metal | Low-H electrode mandatory; diffusible H < 5 ml/100g weld metal |
| Relative site repair complexity | Slightly higher — W-bearing filler required | Standard for 12% Cr family |
For planned maintenance welding on plant, 1.4923 components are marginally easier to work with owing to simpler filler selection. For new-manufacture weld assemblies with controlled, qualified procedures, the practical difference is minimal.
Corrosion & oxidation resistance
Both 1.4935 and 1.4923 achieve corrosion resistance through the 10.5–12.5% chromium passive oxide layer (Cr₂O₃). Above 550 °C, the tungsten in 1.4935 additionally stabilizes this passive layer against steam oxidation, giving a secondary but real advantage in hot gas environments.
| Corrosion environment | 1.4935 performance | 1.4923 performance |
|---|---|---|
| Steam oxidation ≤ 550 °C | Good — stable oxide scale | Good — stable oxide scale |
| Steam oxidation 550–600 °C | Good Advantage | Marginal — oxide growth accelerates |
| Condensate / water droplets | Moderate resistance | Moderate resistance |
| Chloride environments | Limited — not suitable for aggressive Cl⁻ | Limited — not suitable for aggressive Cl⁻ |
| Hot combustion gas with SO₂ | Good up to 600 °C | Good up to 565 °C |
Forging & manufacturing parameters
X20CrMoWV12-1 (1.4935) requires a higher minimum finish-forging temperature (950 °C) than X22CrMoV12-1 (900 °C) due to tungsten's inhibiting effect on recrystallization. Forging below 950 °C risks a mixed-grain structure that compromises final mechanical properties after heat treatment.
| Forging parameter | 1.4935 · X20CrMoWV12-1 | 1.4923 · X22CrMoV12-1 |
|---|---|---|
| Forging temperature range | 1,050 – 1,200 °C | 1,000 – 1,180 °C |
| Min. finish-forging temperature | 950 °C (critical) | 900 °C |
| Reduction ratio (ingot to bar) | ≥ 3:1 | ≥ 3:1 |
| Post-forging cooling | Slow cool — furnace or sand pit | Slow cool — furnace or sand pit |
| Max. single-piece weight (JL) | 30,000 kg | 30,000 kg |
| Seamless ring rolling OD (JL) | Up to 6,000 mm | Up to 6,000 mm |
Jiangsu Liangyi monitors finish-forging temperature with calibrated contact pyrometers at each press stroke on our heavy hydraulic presses. Finish temperature control is a mandatory quality gate enforced on every 1.4935 production lot. Our available product forms — including 1.4935 forged flat bars, seamless rings, and turbine blade stock — are manufactured and certified to this standard.
International standards, designations & equivalents
X20CrMoWV12-1 (EN 1.4935) and X22CrMoV12-1 (EN 1.4923) are governed by EN 10302:2008. International equivalents exist under DIN, ASTM/AISI, GOST, and Japanese JIS systems, with varying compositional tolerances.
| Standard / Country | X20CrMoWV12-1 (1.4935) | X22CrMoV12-1 (1.4923) |
|---|---|---|
| European EN (material no.) | 1.4935 | 1.4923 |
| German DIN designation | X20CrMoWV12-1 | X22CrMoV12-1 |
| Governing material standard | EN 10302:2008 | EN 10302:2008 |
| US AISI / UNS | No direct equivalent — specify EN 1.4935 explicitly | AISI 422 / UNS S42200 (near-equivalent, not identical) |
| Russian GOST (approx.) | 20Kh12WMF-Sh | 20Kh12WMF |
| Fastener product form standard | EN 10269 | EN 10269 |
| General forgings standard | EN 10302:2008 | EN 10302:2008 |
Grade selection guide: when to specify 1.4935 vs 1.4923
The selection rule is straightforward: specify X20CrMoWV12-1 (1.4935) for continuous service temperatures above 530 °C and design lives exceeding 100,000 hours; specify X22CrMoV12-1 (1.4923) for service below 530 °C where cost and availability are priorities.
- ✓Service temperature ≥ 530 °C continuous
- ✓Gas turbine hot-section blades (1st, 2nd stage)
- ✓Steam turbine HP rotors and discs above 550 °C
- ✓Design life ≥ 100,000 hours at elevated temperature
- ✓Maximum creep resistance at 550–600 °C
- ✓Combined-cycle plants with variable thermal cycling
- ✓Long planned inspection intervals required
- ✓Replacement parts for components originally in 1.4935
- ✓Service temperature ≤ 530 °C continuous
- ✓Steam turbine IP / LP blades and vanes
- ✓Valve spindles, stems and fasteners below 550 °C
- ✓Standard design life 60,000–80,000 hours
- ✓Lower material cost is a project priority
- ✓Higher in-country stock availability required
- ✓Simpler on-site repair welding is anticipated
- ✓Older plant retrofits matching original specification
Cost-performance calculation
X20CrMoWV12-1 (1.4935) typically carries a material premium of 8–15% over 1.4923 forgings at equivalent section size, driven by tungsten's raw material cost and the tighter process control requirements at the forge shop. For turbine blade applications operating above 550 °C, this premium is fully justified by extended service life, lower unplanned maintenance risk, and reduced inspection frequency. For IP-stage components below 520 °C, the premium delivers no performance return — 1.4923 is the economically correct specification.
The question is never "which grade is better." The question is always: what is the operating temperature, and what is the required design life? Answer those two questions from your stress analysis, and the grade selection follows directly from the creep data tables.
Engineering team perspective — Jiangsu Liangyi Co., Limited · Jiangyin, Jiangsu, China