Section 01

Why These Two Alloys Are Frequently Compared

Engineers specifying nickel superalloys for high-temperature service in the 550–780 °C range regularly find themselves navigating a short list of precipitation-hardenable candidates. Among European-standard materials, 2.4669 (NiCr15Fe7TiAl) and 2.4652 (NiCr20TiAl) sit at the top of that list.

Both alloys derive their strength from the same fundamental mechanism: the controlled precipitation of the ordered γ' phase (Ni₃(Al,Ti)) within an austenitic nickel-chromium matrix. Both are qualified under EN 10302, both are widely available as large forgings, and both have decades of field history in gas turbines, petrochemical plant, and power generation infrastructure.

Yet the two alloys are not interchangeable. Their different chemistries produce measurably different behaviour in oxidising environments, under sustained creep load, and during the forging process itself. The wrong choice at specification stage can result in premature component retirement, weld repair complications, or — in the case of rotating turbine parts — a costly design requalification.

This article provides the technical depth that datasheets do not: a side-by-side analysis based on our 25+ years of manufacturing both alloys — covering the full production range of NiCr15Fe7TiAl open die forgings and seamless rings from 30 kg to 30,000 kg and 2.4652 components — combined with published literature from EN standards, ASM Handbook Vol. 1, and independent metallurgical research.

A Note on Nomenclature

2.4652 is also listed in EN 10302 as W.Nr. 2.4631 (the creep standard designation) and as W.Nr. 2.4952 (the high-temperature bolt standard). The alloy is chemically identical in all three listings — the different numbers reflect the standard context, not a chemistry variation. Throughout this article, we use 2.4652 as the primary reference.

Section 02

Alloy Chemistry: Where the Differences Begin

Both alloys share a nickel-chromium base and gain strength through titanium- and aluminium-induced γ' precipitation. The key divergences are chromium content, the presence or absence of iron, and the Ti:Al ratio — and each carries engineering consequences.

Chemical Composition — EN 10302 / EN 10269 Nominal Ranges (wt%)
Element 2.4669 NiCr15Fe7TiAl 2.4652 NiCr20TiAl Engineering Implication
NiBalance (~70%)Balance (~73%)Higher Ni in 2.4652 raises γ' solvus temperature
Cr14.0–17.0%18.0–21.0%2.4652 has superior oxidation resistance above 800 °C
Fe5.0–9.0%≤2.0%Fe in 2.4669 lowers γ' solvus — aids forgeability, reduces segregation risk in large sections
Ti2.25–2.75%1.8–2.7%Both rely on Ti for γ' precipitation; similar strengthening potential
Al0.40–1.00%1.0–1.8%Higher Al in 2.4652 increases γ' volume fraction at peak aging temperature
C≤0.08%≤0.06%Lower C in 2.4652 reduces carbide formation, aids weldability
Mo≤0.15%≤0.15%Both essentially Mo-free (unlike Nimonic 80A variants)
Alloy A
2.4669 — NiCr15Fe7TiAl
Alloy 901 / Nimonic 901 equivalent
  • Iron content (5–9%) acts as a matrix diluent, widening the forging temperature window and reducing sensitivity to γ' overaging during slow cooling of large forgings.
  • Lower Cr (14–17%) means less chromium carbide formation at grain boundaries — practical advantage for weld-repaired components.
  • Moderate Ti:Al ratio produces γ' morphology well-suited to fatigue-loaded fasteners that cycle thermally.
  • Iron addition makes this alloy more economical without significant compromise in the 550–700 °C service range.
Alloy B
2.4652 — NiCr20TiAl
Nimonic 80A equivalent (UNS N07080)
  • Higher Cr (18–21%) forms a denser Cr₂O₃ surface oxide layer, providing significantly better oxidation resistance and hot corrosion protection above 750 °C.
  • Near-zero Fe keeps the γ' solvus temperature higher, maintaining precipitate stability at temperatures that would partially dissolve 2.4669's γ'.
  • Higher Al content (1.0–1.8%) increases γ' volume fraction, translating to higher peak strength in fully aged condition.
  • Long industrial history since the 1940s means extensive published creep data and broad code case coverage in ASME and EN standards.
The Iron Variable — More Important Than It Appears

The 5–9% iron in 2.4669 lowers the γ' solvus by approximately 20–30 °C relative to 2.4652. In practical terms, 2.4669 forgings can be solution-treated at lower temperatures while still achieving full γ' dissolution — a significant advantage when processing large-diameter billets (over 600 mm) where temperature gradients across the section make precise solvus targeting critical. For 2.4652, tighter furnace temperature control is essential to avoid under-solution-treating the core of thick sections.

Section 03

Mechanical Properties at Temperature

Room-temperature strength comparisons between these two alloys are largely academic for engineering applications — what matters is retained strength, ductility, and toughness at service temperatures.

Typical Mechanical Properties — Fully Heat-Treated Forgings
Property Test Temp. 2.4669 2.4652 Notes
0.2% Proof Stress (Rp0.2)20 °C≥650 MPa≥720 MPa2.4652 higher due to greater γ' volume fraction
Tensile Strength (Rm)20 °C≥1,000 MPa≥1,080 MPa2.4652 advantage narrows at elevated temperature
Elongation (A)20 °C≥18%≥18%Both alloys ductile; similar forming behaviour
0.2% Proof Stress550 °C≥600 MPa≥660 MPa2.4652 retains slightly more strength
0.2% Proof Stress700 °C≥520 MPa≥580 MPaGap widens above 650 °C
Impact Energy (KV)20 °C≥60 J≥40 J2.4669 notably tougher — better for fasteners under shock loading
Hardness20 °C262–321 HB280–341 HB2.4652 harder; more demanding to machine
Tensile Strength at Room Temperature 2.4652 leads by ~8%
2.4669 (~1,000 MPa)
2.4652 (~1,080 MPa)
Impact Toughness (KV) 2.4669 leads by ~50%
2.4669 (≥60 J)
2.4652 (≥40 J)
Oxidation Resistance at 750 °C 2.4652 significantly better
2.4669 (moderate Cr₂O₃ layer)
2.4652 (dense protective oxide)

The toughness advantage of 2.4669 is a frequently underappreciated differentiator. Turbine fasteners and high-temperature bolts must survive not just steady-state thermal loading but transient shock events — start-up thermal cycles, pressure excursions, and maintenance handling. The significantly higher impact energy of 2.4669 makes it the safer choice for bolted joints where brittle fracture would have catastrophic consequences.

Section 04

Heat Treatment and Precipitation Response

Both alloys require a two-stage heat treatment — solution annealing followed by aging — to develop their full mechanical properties. The details differ significantly, with practical implications for forging manufacturers and end users alike.

2.4669
NiCr15Fe7TiAl — Solution + Double Age
Step 1 — Solution Anneal
980–1020 °C / air cool or faster
Lower solvus (Fe effect) means full γ' dissolution at lower temperatures — reduced grain growth risk.
Step 2 — Primary Age
760–790 °C / 16 h / air cool
Nucleates fine γ' precipitate dispersion with optimised particle size for fatigue and creep resistance.
Step 3 — Secondary Age
700–730 °C / 16 h / air cool
Stabilises precipitate morphology and relieves residual stress from primary aging.
2.4652
NiCr20TiAl — Solution + Single Age
Step 1 — Solution Anneal
1040–1080 °C / air cool or oil quench
Higher solvus demands higher temperatures — critical for large ring or disc forgings to ensure core dissolution.
Step 2 — Age
700–760 °C / 16 h / air cool
Precipitates a higher volume fraction of γ' than 2.4669 at equivalent temperature due to higher Al content.
Note
Double age available for bolting per EN 10269
Higher solution temperature in large forgings requires careful furnace uniformity control — our PLC furnaces provide ±5 °C uniformity.
Large Forging Heat Treatment — Manufacturing Note

For 2.4652 forgings over 500 mm cross-section, we implement a dedicated ramp-rate protocol: heating at ≤80 °C/hour below 600 °C, then ≤120 °C/hour to solution temperature. This prevents thermal gradients that cause differential γ' dissolution and subsequent property variation between surface and core. Combined with post-solution quench in forced-air or oil, this protocol eliminates the core under-aging issue that can occur in large 2.4652 forgings processed with insufficiently controlled furnace cycles.

Section 05

Creep Resistance: The Long-Term Story

For rotating and stationary components in gas turbines and industrial furnaces, creep — not tensile strength — is usually the life-limiting failure mode. Creep resistance governs component wall thickness, maintenance intervals, and the maximum allowable operating temperature.

Typical Creep and Stress Rupture Data (Published Literature Values)
Test Condition 2.4669 — Limiting Stress (MPa) 2.4652 — Limiting Stress (MPa) 2.4652 Advantage
1% creep in 1,000 h at 600 °C~430 MPa~480 MPa+12%
1% creep in 1,000 h at 650 °C~320 MPa~390 MPa+22%
1% creep in 1,000 h at 700 °C~190 MPa~260 MPa+37%
Rupture in 1,000 h at 650 °C~370 MPa~440 MPa+19%
Rupture in 10,000 h at 650 °C~280 MPa~350 MPa+25%

The creep advantage of 2.4652 grows markedly with temperature — at 600 °C the gap is modest, but by 700 °C it becomes substantial (+37%). The physical explanation lies in the combination of higher γ' volume fraction (from greater Al content) and higher γ' solvus temperature (from zero Fe). These factors delay γ' coarsening under sustained load at elevated temperature, which is the primary mechanism of creep strain accumulation in precipitation-hardened nickel alloys.

When 2.4669's Creep Properties Are Sufficient

For applications at or below 620 °C — including the majority of steam turbine fastening applications and many petrochemical valve stems — 2.4669's creep performance is entirely adequate and is specified in both EN 10269 (fasteners) and in multiple industrial codes. The alloy's superior toughness and easier machinability then tip the overall balance in its favour. Specifying 2.4652 in this temperature band provides no functional benefit and adds cost.

Section 06

Oxidation and Corrosion Resistance

In oxidising environments, chromium content is the dominant variable. The protective Cr₂O₃ scale that forms on both alloys provides a barrier against further oxidation, but its integrity and self-healing capacity depend on the matrix chromium level. The 3–4% Cr advantage of 2.4652 translates into a measurably denser oxide layer.

Cr 14–17% (lower)
Chromium Content
Cr 18–21% (higher)
~750 °C continuous limit
Oxidation Limit
~900 °C continuous limit
Moderate sulphidation resistance
Hot Corrosion Type I
Good sulphidation resistance
Adequate for most industrial service
Carburisation
Better in oxidising/carburising mix

For gas turbine components exposed directly to combustion gases or exhaust streams — nozzle guide vane carriers, combustion casing segments, flue gas valve bodies — 2.4652's oxidation advantage is often the deciding factor. In enclosed systems where oxygen partial pressure is controlled (such as ammonia converters, hydrogen reformers, or nuclear heat exchangers), the oxidation advantage matters less, and 2.4669's toughness and weldability become more relevant.

Section 07

Forgeability and Manufacturing Considerations

2.4669
Forging Notes
  • Iron content widens the hot working temperature range, reducing surface cracking risk during heavy reductions. We routinely forge 2.4669 rounds up to 1,200 mm diameter on our 8,000-tonne press.
  • Lower γ' solvus means the matrix remains more workable over a broader thermal window during billet reheating.
  • Responds well to standard billet reheating in gas-fired furnaces without requiring inert atmosphere — reducing production cost.
  • Machinability: carbide tooling at feeds of 0.1–0.25 mm/rev delivers good results. HSS tooling not recommended above HRC 32.
2.4652
Forging Notes
  • Higher Cr and no-Fe matrix produces a narrower hot-working window — typically 100–120 °C narrower than 2.4669. More frequent reheating cycles required for large forgings.
  • More sensitive to surface oxidation during forging; scale management is critical to avoid oxide inclusion entrainment in the near-surface zone.
  • Ring rolling of 2.4652 to OD ≥3,000 mm requires careful feed rate control to avoid surface cracking at the ring ID. We have rolled 2.4652 rings up to 4,200 mm OD.
  • Machinability is harder than 2.4669. Ceramic or PCBN tooling is preferred for final finish cuts; cutting speeds 15–20% lower than 2.4669 equivalents.
VIM + ESR Melting for Both Alloys

At Jiangsu Liangyi, all 2.4669 and 2.4652 forgings are produced from double-melt (VIM + ESR) or triple-melt (VIM + ESR + VAR) ingots depending on section size and application. This ensures tight compositional control and low inclusion content required for high-cycle fatigue applications. For turbine disc blanks in 2.4652 above 1,500 kg, we specify VAR as the final melt step as standard practice.

Section 08

Application Mapping: Which Alloy Fits Which Component

Based on the property analysis above, the following application mapping reflects our engineering team's practical guidance — drawn from our forging supply history across gas turbine OEMs, petrochemical EPC contractors, and nuclear power plant operators worldwide.

Specify 2.4669 When...
NiCr15Fe7TiAl Is the Better Choice
  • High-temperature fasteners and bolting (EN 10269 applications, ≤650 °C service)
  • Valve stems, spindles, and guide rods in steam service (550–680 °C)
  • Components requiring high impact toughness or shock resistance
  • Applications where complex weld repair may be needed
  • Large-section forgings (over 600 mm diameter) where core heat treatment uniformity is difficult
  • Cost-sensitive projects where 2.4652's full oxidation/creep capability is not required
  • Turbine blade blanks for service temperatures below 700 °C
  • Structural components in industrial furnaces (non-oxidising atmosphere)
Specify 2.4652 When...
NiCr20TiAl Is the Better Choice
  • Gas turbine discs and blisk blanks in continuous high-temperature service (650–800 °C)
  • Combustion casing segments and liner components exposed to hot gas streams
  • Nozzle vane carriers and guide ring forgings
  • Applications where sustained creep resistance above 650 °C is life-limiting
  • Components in oxidising or mixed oxidising/sulphidising environments
  • High-temperature seal rings operating at or above 750 °C
  • Aerospace structural forgings where maximum strength-to-weight is required
  • High-temperature springs and retaining rings requiring peak γ' hardening
Section 09

Standards, Certifications, and Procurement

Standards Coverage — 2.4669 and 2.4652
Standard Scope 2.4669 2.4652
EN 10269Fasteners and bolting at elevated temperaturePrimary designationAlso listed (as 2.4952)
EN 10302Creep-resisting steels and nickel alloysListedListed (as 2.4631)
EN 10204 3.1Inspection certificate typeStandard supplyStandard supply
EN 10204 3.2Third-party witnessed inspectionSupported on request (client nominates body)Supported on request (client nominates body)
ASME SB-637US material standard for nickel alloy forgings (UNS N07080)No direct ASTM/UNS equivalent listedUNS N07080 is listed in ASME SB-637 (compliance requires ASME-authorised certification)
AMS 5828US aerospace material specificationNot applicableNimonic 80A / UNS N07080 referenced in AMS 5828 (aerospace compliance requires AS9100 or equivalent)
NACE MR0175 / ISO 15156Sour service hardness limits (oil & gas)Hardness ≤HRC 33 achievable; compliance is end-user's responsibilityHardness ≤HRC 33 achievable; compliance is end-user's responsibility

For US-market projects specifying ASME or AMS requirements, 2.4652 (as UNS N07080 / Nimonic 80A) has broader direct coverage, whereas 2.4669 typically requires a material equivalency review. For European power generation and petrochemical procurement, both alloys are well-covered by EN standards and can be supplied with EN 10204 3.1 certificates as standard.

All forgings we supply are permanently marked by low-stress dot-peen stamping with the full heat number, material designation, standard reference, and our manufacturer identification code — providing complete traceability from ingot to finished component.

Section 10

Decision Framework: A Practical 3-Question Guide

Reduce alloy selection to three questions. Answer them in order — the first question that gives a clear answer stops the process.

Question
→ Specifies 2.4669
→ Specifies 2.4652
Q1
Is maximum service temperature above 700 °C?
No — max temp ≤700 °C → continue to Q2
Yes — max temp >700 °C → specify 2.4652
Q2
Is the component a bolted joint, fastener, or stem that must survive thermal cycling and shock loading?
Yes — fastener/bolt application → specify 2.4669 for toughness advantage
No — rotating or stationary structural part → continue to Q3
Q3
Is sustained creep resistance at 640–700 °C the primary design constraint?
No — other constraints dominate → consider 2.4669 for cost efficiency
Yes — creep life is life-limiting → specify 2.4652
Still Unsure? Talk to Our Engineering Team

Approximately 15% of high-temperature forging enquiries involve application conditions where neither alloy is clearly superior, or where procurement constraints override a purely technical choice. Our metallurgical engineers provide free application review as part of the quotation process — send us your operating conditions and we will give you our recommendation in writing, along with the technical reasoning.

Once you have selected the right alloy, the next step is sizing the forging. If your application calls for 2.4669, our product page covers available sizes, EN 10302 heat treatment conditions (+P980 / +P1170), and how to submit a technical enquiry. Both alloys are supplied with EN 10204 3.1 certificates and full NDT documentation as standard. Third-party witness inspection by client-nominated inspection bodies, and NACE MR0175-compatible hardness control, are available on request.

Request a Custom Forging Quotation
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